An overview of the synthesis of graphene by liquid-phase exfoliation: mechanisms, factors, and techniques

Authors

  • Carlos Daniel Galindo-Uribe CinvestavDepartamento de Química, Centro de Investigación y Estudios Avanzados del Instituto Politécnico Nacional, Ciudad de México, México, Mexico https://orcid.org/0000-0003-3262-3694
  • Patrizia Calaminici Departamento de Química, Centro de Investigación y Estudios Avanzados del Instituto Politécnico Nacional, Ciudad de México, México, Mexico https://orcid.org/0000-0001-9842-4271
  • Omar Solorza-Feria Departamento de Química, Centro de Investigación y Estudios Avanzados del Instituto Politécnico Nacional, Ciudad de México, México, Mexico https://orcid.org/0000-0003-2084-0659

DOI:

https://doi.org/10.15359/ru.36-1.35

Keywords:

graphene, exfoliation, materials, synthesis

Abstract

The objective of this article is to create a consensus about the graphene production by the liquid-phase exfoliation (LPE) method, as well as to understand the key causes and factors affecting the yield and quality of the graphene obtained. An exhaustive bibliographic search was conducted in Google Scholar given the extent of its collection. The results of the search are ordered by relevance, giving priority to key causes and physical phenomena related to LPE. The articles focused on understanding physical and chemical phenomena were classified in the mechanism section, in order to have a better understanding of the method at the molecular level. With this information, a classification of the most common LPE techniques (sonication, microfluidics, etc.) is proposed in order to reach a consensus on which techniques belong to the LPE method in function of their mechanism. The proposed classification aims at developing new techniques to significantly improve the performance of this method. From this systematic review, it is concluded that the liquid-phase exfoliation method is robust and very attractive to the industry and has easy scalability with high performance in relation to the techniques analyzed.

References

Abdelkader, A. M. (2015). How to get between the sheets: a review of recent works on the electrochemical exfoliation of graphene materials from bulk graphite. Nanoscale, 7(16), 6944-6956. https://doi.org/10.1039/C4NR06942K

Amiri, A. N. (2018). A review on liquid-phase exfoliation for scalable production of pure graphene, wrinkled, crumpled and functionalized graphene and challenges. FlatChem, 8, 40-71. https://doi.org/10.1016/j.flatc.2018.03.004

Beel, J. G. (2010). Academic Search Engine Optimization (aseo) Optimizing Scholarly Lit-erature for Google Scholar & Co. Journal of Scholarly Publishing, 41(2), 176-190. https://doi.org/10.1353/scp.0.0082

Botto, L. (2019). Toward Nanomechanical Models of Liquid-Phase Exfoliation of Layered 2D Nanomaterials: Analysis of a π−peel Model. Frontiers in Materials, 6, 302. https://doi.org/10.3389/fmats.2019.00302

Chen, K. W. (2018). Graphene-based materials for flexible energy storage devices. Journal of Energy Chemistry, 27(1), 12-24. https://doi.org/10.1016/j.jechem.2017.08.015

Cheng, Z. L. (2020). Ultrasound-assisted Li+/Na+ co-intercalated exfoliation of graphite into few-layer graphene. Ultrasonics sonochemistry, 66, 105108. https://doi.org/10.1016/j.ultsonch.2020.105108

Choi, C. H. (2020). Microfluidics for Two-Dimensional Nanosheets: A Mini Review. Pro-cesses, 8, 1067. https://doi.org/10.3390/pr8091067

Chung, D. (2016). Graphite Intercalation Compounds. En Reference Module in Materials Science and Materials Engineering (pp. 1-5). https://doi.org/10.1016/B978-0-12-803581-8.02311-0

Ciesielski, A. & Samori, P. (2014). Graphene via sonication assisted liquid-phase exfolia-tion. Chemical Society Reviews, 43(1), 381-398. https://doi.org/10.1039/C3CS60217F

Coleman, J. N. (2013). Liquid exfoliation of defect-free graphene. Accounts of Chemical Research, 46(1), 14-22. https://doi.org/10.1021/ar300009f

Ding, J. Z. (2018). A water-based green approach to large-scale production of aqueous compatible graphene nanoplatelets. Scientific Reports, 8(1), 1-8. https://doi.org/10.1038/s41598-018-23859-5

Du, W. L. (2013). Organic salt-assisted liquid-phase exfoliation of graphite to produce high-quality graphene. Chemical Physics Letters, 568, 198-201. https://dx.doi.org/10.1016/j.cplett.2013.03.060

Geim, A. N. (2007). The rise of graphene. Nature Materials, 6, 183–191. https://doi.org/10.1038/nmat1849

Guardia, L. F.-M.-F.-R.-A. (2011). High-throughput production of pristine graphene in an aqueous dispersion assisted by non-ionic surfactants. Carbon, 49(5), 1653-1662. https://doi.org/10.1016/j.carbon.2010.12.049

Halim, U. Z. (2013). A rational design of cosolvent exfoliation of layered materials by di-rectly probing liquid–solid interaction. Nature Communications, 4(1), 1-7. https://doi.org/10.1038/ncomms3213

Hernandez, Y. L. (2010). Measurement of multicomponent solubility parameters for gra-phene facilitates solvent discovery. Langmuir, 26(5), 3208-3213. https://doi.org/10.1021/la903188a

Hernandez, Y. N. (2008). High-yield production of graphene by liquid-phase exfoliation of graphite. Nature Nanotechnology, 3(9), 563-568. https://doi.org/10.1038/nnano.2008.215

Huang, H. X. (2012). Highly efficient electrolytic exfoliation of graphite into graphene sheets based on Li ions intercalation–expansion–microexplosion mechanism. Journal of Materials Chemistry, 22(21), 10452-10456. https://doi.org/10.1039/C2JM00092J

Karagiannidis, P. G. (2017). Microfluidization of graphite and formulation of graphene-based conductive inks. ACS Nano, 11(3), 2742-2755. https://doi.org/10.1021/acsnano.6b07735

Kim, J. K. (2015). Direct exfoliation and dispersion of two-dimensional materials in pure water via temperature control. Nature Communications, 6(1), 1-9. https://doi.org/10.1038/ncomms9294

Kokai, F. S. (2012). Ultrasonication fabrication of high quality multilayer graphene flakes and their characterization as anodes for lithium ion batteries. Diamond and Related Materials, 29, 63-68. https://dx.doi.org/10.1016/j.diamond.2012.07.011

Kovtyukhova, N. I.-S. (2014). Non-oxidative intercalation and exfoliation of graphite by Brønsted acids. Nature Chemistry, 6(11), 957–963. https://doi.org/10.1038/nchem.2054

Lee, X. J.-G. (2019). Review on graphene and its derivatives: Synthesis methods and po-tential industrial implementation. Journal of the Taiwan Institute of Chemical Engi-neers, 98, 163-180. https://doi.org/10.1016/j.jtice.2018.10.028

Li, Z. Y. (2020). Mechanisms of liquid-phase exfoliation for the production of graphene. ACS Nano, 14(9), 10976-10985. https://doi.org/10.1021/acsnano.0c03916

Ma, H. & Shen, Z. (2020). Exfoliation of graphene nanosheets in aqueous media. Ceramics International, 46(14), 21873-21887. https://doi.org/10.1016/j.ceramint.2020.05.314

Manna, K. H. (2016). Toward understanding the efficient exfoliation of layered materials by water-assisted cosolvent liquid-phase exfoliation. Chemistry of materials, 28(21), 7586-7593. https://doi.org/10.1021/acs.chemmater.6b01203

Notley, S. M. (2012). Highly Concentrated Aqueous Suspensions of Graphene through Ul-trasonic Exfoliation with Continuous Surfactant Addition. Langmuir, 28, 14110−14113. https://dx.doi.org/10.1021/la302750e

Parvez, K. L. (2013). Electrochemically exfoliated graphene as solution-processable, highly conductive electrodes for organic electronics. ACS Nano, 7(4), 3598-3606. https://doi.org/10.1021/nn400576v

Parviz, D. I. (2016). Challenges in liquid‐phase exfoliation, processing, and assembly of pristine graphene. Advanced Materials, 28(40), 8796-8818. https://doi.org/10.1002/adma.201601889

Paton, K. R. (2014). Scalable production of large quantities of defect-free few-layer gra-phene by shear exfoliation in liquids. Nature Materials, 13(1), 624–630. https://doi.org/10.1038/nmat3944

Perreault, F. D. (2015). Environmental applications of graphene-based nanomaterials. Chemical Society Reviews, 44(16), 5861-5896. https://doi.org/10.1039/C5CS00021A

Raccichini, R. V. (2015). The role of graphene for electrochemical energy storage. Nature Materials, 14(3), 271-279. https://doi.org/10.1038/nmat4170

Rüdorff, W. & Siecke, W. (1958). Graphitsalze von organischen Säuren. Graphit‐trifluoracetat und Graphit‐borfluoriddiacetat. Chemische Berichte, 91(6), 1348-1354. https://doi.org/10.1002/cber.19580910636

Shen, J. H. (2015). Liquid phase exfoliation of two-dimensional materials by directly prob-ing and matching surface tension components. Nano Letters, 15(8), 5449-5454. https://doi.org/10.1021/acs.nanolett.5b01842

Vallés, C. D. (2008). Solutions of Negatively Charged Graphene Sheets and Ribbons. Journal of the American Chemical Society, 130(47), 15802–15804. https://doi.org/10.1021/ja808001a

Wang, Y. Z. (2017). Liquid phase exfoliation of graphite into few-layer graphene by soni-cation and microfluidization. Materials Express, 7(6), 491-499. https://doi.org/10.1166/mex.2017.1395

Xu, Y. C. (2018). Liquid-Phase exfoliation of graphene: An overview on exfoliation media, techniques, and challenges. Nanomaterials, 8(11), 942. https://doi.org/10.3390/nano8110942

Yi, M. S. (2012). Achieving concentrated graphene dispersions in water/acetone mixtures by the strategy of tailoring Hansen solubility parameters. Journal of Physics D: Ap-plied Physics, 46(2), 025301. https://doi.org/10.1088/0022-3727/46/2/025301

Yi, M. S. (2014). Kitchen blender for producing high-quality few-layer graphene. Carbon, 78, 622-626. https://dx.doi.org/10.1016/j.carbon.2014.07.035

Zhang, X. C. (2010). Dispersion of graphene in ethanol using a simple solvent exchange method. Chemical Communications, 46(40), 7539-7541. https://doi.org/10.1039/C0CC02688C

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Published

2022-06-01

Issue

Vol. 36 No. 1 (2022): Uniciencia. January-December, 2022

Section

Original scientific papers (evaluated by academic peers)

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